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- W2029509717 abstract "Zinc phosphide may have potential for photovoltaic applications due to its high absorptivity of visible light and the earth abundance of its constituent elements. Two different solution-phase synthetic strategies for phase-pure and crystalline Zn3P2 nanoparticles (∼3–15 nm) are described here using dimethylzinc and vary with phosphorus source. Use of tri-n-octylphosphine (TOP) with ZnMe2 takes place at high temperatures (∼350 °C) and appears to proceed via rapid in situ reduction to Zn(0), followed by subsequent reaction with TOP over a period of several hours to produce Zn3P2 nanoparticles. Some degree of control over size was obtained through variance of the TOP concentration in solution; the average size of the particles decreases with increasing TOP concentration. With the more reactive phosphine, P(SiMe3)3, lower temperatures, ∼150 °C, and shorter reaction times (1 h) are required. When P(SiMe3)3 is used, the reaction mechanism most likely proceeds via phosphido-bridged dimeric Zn(II) intermediates, ..." @default.
- W2029509717 created "2016-06-24" @default.
- W2029509717 creator A5005666807 @default.
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- W2029509717 creator A5058851361 @default.
- W2029509717 creator A5071172724 @default.
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- W2029509717 date "2014-03-03" @default.
- W2029509717 modified "2023-09-26" @default.
- W2029509717 title "Phase-Pure Crystalline Zinc Phosphide Nanoparticles: Synthetic Approaches and Characterization" @default.
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- W2029509717 doi "https://doi.org/10.1021/cm500557f" @default.
- W2029509717 hasPublicationYear "2014" @default.
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