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• W2029543713 abstract "A convenient synthesis of novel 2,2,4-trisubstituted pyrrolidines via stereoselective 5-exo iodocyclization of the 2,2-disubstituted olefins 8 and 9 is described. Single crystal X-ray analysis of the oxazolidinone 15 confirmed the relative stereochemistry in this cyclization. As observed earlier in the formation of 2,2,4-trisubstituted tetrahydrofurans, the presence of a bulky aryl substituent on the olefin appears to direct the stereochemical outcome of these halocyclizations." @default.
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• W2029543713 date "2003-10-01" @default.
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• W2029543713 title "A highly stereoselective approach to novel 2,2,4-substituted pyrrolidines by halocylization: key intermediates towards syntheses of nitrogen analogs of Noxafil®" @default.
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• W2029543713 doi "https://doi.org/10.1016/j.tetlet.2003.08.114" @default.
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