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• W2029559935 startingPage "15114" @default.
• W2029559935 abstract "A novel approach to synthesize symmetric 1,7-dicarbonyl compounds via a tandem radical addition–elimination–addition reaction of S-carbonylmethyl xanthates with allylmethylsulfone and its analogues has been developed. Radicals were produced from S-carbonylmethyl xanthates by adding dilauroyl peroxide and reacted with allylmethylsulfone or analogues to generate terminal olefins as intermediates. The excessive radicals reacted with the intermediate olefins immediately to give adducts of symmetric 1,7-dicarbonyl compounds. This is an efficient method to synthesize 1,7-dicarbonyl compounds under mild conditions." @default.
• W2029559935 created "2016-06-24" @default.
• W2029559935 creator A5010946067 @default.
• W2029559935 creator A5046676415 @default.
• W2029559935 date "2013-01-01" @default.
• W2029559935 modified "2023-10-16" @default.
• W2029559935 title "One-pot synthesis of symmetric 1,7-dicarbonyl compounds via a tandem radical addition–elimination–addition reaction" @default.
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• W2029559935 doi "https://doi.org/10.1039/c3ra42932f" @default.
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