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• W2029561936 endingPage "182" @default.
• W2029561936 startingPage "173" @default.
• W2029561936 abstract "The technical feasibility for Fischer–Tropsch synthetic fuels production over different cobalt/SiC catalysts was studied. Silicon carbide-supported catalysts were prepared by means of incipient wetness impregnation (IWI) and characterized by N2 adsorption/desorption, acid/base titrations, XRD, TEM, TPR and pulse oxidation techniques. The bench scale catalytic performance was examined at a total pressure of 20 bar, a temperature range between 220 and 250 °C, a space velocity (GHSV) of 6000 N cm3 g−1 h−1 and using syngas with H2/CO molar ratio equal to 2. For SiC-supported catalysts, the use of a certain amount of calcium as promoter resulted in a higher basicity and a slight higher cobalt dispersion. Furthermore, particle size and the degree of reduction were found to be directly influenced by the cobalt loading. A maximum extent of reduction was found at 12–15 wt.% cobalt with little dependence on the addition of promoter. Catalytic activity provided promising Fischer–Tropsch performance with C5+ selectivity values higher than 90% in all the cases and especially on promoted catalysts (higher than 95%). In addition, promoted catalysts shifted C5+ hydrocarbon product distribution to higher molecular weight demonstrating that different commercial synthetic fuels formulations (gasoline to diesel) can be provided by modifying mCo-nCa/SiC catalyst composition." @default.
• W2029561936 created "2016-06-24" @default.
• W2029561936 creator A5000386135 @default.
• W2029561936 creator A5016215387 @default.
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• W2029561936 creator A5040090406 @default.
• W2029561936 creator A5062708666 @default.
• W2029561936 creator A5073447257 @default.
• W2029561936 date "2012-06-01" @default.
• W2029561936 modified "2023-10-14" @default.
• W2029561936 title "FTS fuels production over different Co/SiC catalysts" @default.
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