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- W2029595539 abstract "The reaction of ȮH radicals with thiosulphate ions in aqueous solutions leads to intermediates identified as S2O3OH2- (λmax = 320 nm, ϵ320 = (0.8 ± 0.2) × 102m2mol-1), S4O63- (λmax = 420 nm, ϵ420 = (4.2 ± 0.9) × 102m2mol-1) and S2O3 (λmax = 370 nm). The proposed mechanism, (1) ȮH + S2O32- → S2O3OH2-k1 = (7.8 ± 2.1) × 109 dm3 mol-1 s-1 (2) S2O3OH2- + S2O32- → S4O63- + OH-k2 = (6 ± 2) × 108dm3mol-1s-1 (3) S4O63- → S2O3- + S2O32-k3 = (2.5 ± 0.3) × 106s-1 (4) 2 S2O3- → products 2 k4 = (1.9 ± 0.5) × 109dm3mol-1s-1" @default.
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- W2029595539 date "1984-01-01" @default.
- W2029595539 modified "2023-10-16" @default.
- W2029595539 title "Pulse radiolysis of aqueous solutions of thiosulphate" @default.
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- W2029595539 doi "https://doi.org/10.1016/0146-5724(84)90138-9" @default.
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