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- W2029600162 abstract "We have investigated the self-assembly of 2,4,6-tris(2-pyridyl)-1,3,5-triazine (TPTZ) molecule on Au(111) surface using an ultrahigh vacuum low-temperature scanning tunneling microscope. The TPTZ molecules form enantiomorphous domains composed of rhombic supercells with various periods depending on the coverage of molecules, that is, “1 × 1” and “2 × 2” structures at low coverages, and “6 × 6”, “7 × 7”, and “8 × 8” structures at higher coverages. In a unit cell of a certain enantiomer, the two triangular half-unit cells, consisting of adsorbed TPTZ molecules, are centrosymmetric to each other. The molecules inside each half-unit cell are bound to each other through a single −CH···N− hydrogen bond, while the molecules at the boundaries between half-unit cells are bound through double −CH···N− hydrogen bonds. The STM images and the DFT calculations reveal that the molecules in an enantiomorphous domain adopt the same adsorption orientation of either R-TPTZ or L-TPTZ, which indicates that the adsorbed TPTZ molecules on Au(111) undergo spontaneous chiral resolution. The subtle balance between the intermolecular interaction and the molecule−substrate interaction tunes the period of the superstructure. The total interaction energy densities obtained from the DFT calculations explain the experimental observations quantitatively." @default.
- W2029600162 created "2016-06-24" @default.
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- W2029600162 date "2009-04-01" @default.
- W2029600162 modified "2023-09-24" @default.
- W2029600162 title "Spontaneous Chiral Resolution in Supramolecular Assembly of 2,4,6-Tris(2-pyridyl)-1,3,5-triazine on Au(111)" @default.
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- W2029600162 doi "https://doi.org/10.1021/ja9001986" @default.
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