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• W2029602662 endingPage "609" @default.
• W2029602662 startingPage "599" @default.
• W2029602662 abstract "Abstract The review provides a survey of the key classes of Pt II complexes containing cis ‐{Pt(η 1 ‐hydrocarbyl)(η 2 ‐unsaturated ligand)} moieties, which have been isolated or at least unequivocally characterized in solution. These compounds, which mimic reactive intermediates of fundamental catalytic processes, have been classified in four general types, which display a cis arrangement of an alkyl group and a monoalkene ( I ), an aryl group and a monoalkene ( II ), an alkyl group and a monoalkyne ( III ), and an aryl group and a monoalkyne ( IV ). A discussion of their main structural and chemicalfeatures, disclosing the factors affecting their reactivity, dynamic behavior, and relative stability, is presented. In some remarkable cases ( III and IV ), it is the cis arrangement of the hydrocarbyl fragments that promotes unusual reactivity." @default.
• W2029602662 created "2016-06-24" @default.
• W2029602662 creator A5017424000 @default.
• W2029602662 creator A5060385126 @default.
• W2029602662 date "2012-01-10" @default.
• W2029602662 modified "2023-09-24" @default.
• W2029602662 title "Synthesis and Reactivity of Square‐Planar Pt ^II –η ¹ ‐Hydrocarbyl Complexes Containing <i>cis</i> ‐Coordinated Olefin or Alkyne" @default.
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• W2029602662 doi "https://doi.org/10.1002/ejic.201101148" @default.
• W2029602662 hasPublicationYear "2012" @default.
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