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- W2029603025 abstract "Electrochemical behavior of a series of halogenated acids such as monochloroacetic acid, dichloroacetic acid, trichloroacetic acid, bromoacetic acid, α-bromopropionic acid, 2-bromobutyric acid, and 4-bromobutyric acid at C60-octasodium calix[8]aryloxy octakis-(propane-3-sulphonate) (represented as C60-L) and Nafion chemically modified electrodes in mixed acetonitrile and water (3:2, v:v) was investigated systematically and comparatively by cyclic voltammetry. It was found that C60-L/Nafion is capable of mediating the electron transfer to α-halogenated organic acid, showing it could be used to catalytically reduce the above organohalide compounds, except for 4-bromobutyric acid. Values of the rate constant, k, for the electrocatalytic dehalogenation of monochloroacetic acid, dichloroacetic acid, and trichloroacetic acid by C60-L anion were determined by using the rotating-disk electrode voltammetry." @default.
- W2029603025 created "2016-06-24" @default.
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- W2029603025 date "2000-09-01" @default.
- W2029603025 modified "2023-09-27" @default.
- W2029603025 title "Electrocatalytic reduction of halogenated acid at electrodes chemically modified with C60-octasodium calix[8]aryloxy octakis-(propane-3-sulphonate) complex and Nafion films" @default.
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- W2029603025 doi "https://doi.org/10.1016/s0013-4686(00)00501-6" @default.
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