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- W2029605725 abstract "Exo,exo derivatives of the efficient catalyst precursors (diisodicyclopentadienyl)titanium and -zirconium dichloride substituted at the central position have been synthesized. These compounds have been characterized by solution NMR measurements, which also permitted the calculation of rotational barriers. The solid-state structures of exo,exo-bis(3-diphenylphosphinoisodicyclopentadienyl)titanium and -zirconium dichloride were determined by X-ray crystallography. Unfortunately, after activation by methylalumoxane, these complexes are shown to serve as poor catalysts for the polymerization of propene." @default.
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- W2029605725 date "1998-10-01" @default.
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- W2029605725 title "Some New <i>exo,exo</i>-Bis(isodicyclopentadienyl)titanium and -zirconium Dichloride Derivatives: Synthesis, Characterization, and Evaluation as Propene Polymerization Catalysts" @default.
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- W2029605725 doi "https://doi.org/10.1021/om980542d" @default.
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