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• W2029610022 abstract "Abstract The experimental data of densities (ρ), speeds of sound (u) and refractive indices (nD) of aqueous binary mixtures of different glycol ethers, namely, ethylene glycol monomethyl ether (EGMME), ethylene glycol monoethyl ether (EGMEE), diethylene glycol monomethyl ether (DEGMME) and diethylene glycol monoethyl ether (DEGMEE) over the entire composition range, at two different temperatures i.e. 278.15 K and 288.15 K and at one atmospheric pressure have been reported. Different derived parameters such as apparent molar volumes (∅V) of solute, excess molar volume (VE) of solution, isentropic compressibility (βS) of the solution, apparent molar isentropic compressibility (∅KS) of the solute have been computed. The limiting apparent molar volume of solutes (∅V0) and limiting apparent molar isentropic compressibility of solute (∅KS0) have been obtained for aqueous binary mixtures of these glycol ether by smooth extrapolation of ∅V–x2 and ∅KS–x2 curves to zero concentration, respectively. By using the values of ∅V0, the limiting excess partial molar volumes V ¯ 2 0 E have also been calculated. The values of excess molar volume (VE) of the solution were fitted in Redlich–Kister polynomial to obtain the coefficients of fitting equation. The results obtained in this study have been interpreted in terms of different interactions among solute and solvent molecules such as hydrogen bonding, solute–solute and solute–solvent interaction." @default.
• W2029610022 created "2016-06-24" @default.
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• W2029610022 date "2013-07-01" @default.
• W2029610022 modified "2023-09-27" @default.
• W2029610022 title "Investigations of volumetric, acoustic and optical properties of aqueous binary mixtures of different glycol ethers at temperatures 278.15K and 288.15K" @default.
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• W2029610022 doi "https://doi.org/10.1016/j.molliq.2013.04.009" @default.
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