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- W2029616895 abstract "Dermatan sulfate in the solid state has been studied by 13C CPMAS nmr and X-ray diffraction in order to establish the ring conformation of the L-iduronate moiety. The solid state nmr spectrum is similar to the solution spectrum obtained previously, indicating that a ring conformation at least approximating to 1C4 predominates in the solid state. X-ray powder diffraction data from the same sample indicate the presence of the 8-fold helix form previously observed by fiber diffraction, and interpreted in terms of a 4C1 ring form. A likely explanation of the results is that a distorted 1C4L-iduronate ring conformation, not considered in the initial X-ray analysis, may emerge to provide a satisfactory interpretation of all available physicalchemical data." @default.
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- W2029616895 date "1986-05-01" @default.
- W2029616895 modified "2023-09-27" @default.
- W2029616895 title "Solid-state 13C NRM and X-ray diffraction of dermatan sulfate" @default.
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- W2029616895 doi "https://doi.org/10.1016/0006-291x(86)91179-4" @default.
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