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- W2029649448 abstract "Five new supramolecular lanthanide coordination polymers with three different structures, {[La2(IA)3(phen)2] · 2H2O}n (1), {[Ln(IA)1.5(phen)] · xH2O}n [x = 1, Ln = Eu (2); x = 0.25, Ln = Dy (3)], and [Ln(IA)1.5(phen)]n [Ln = Er (4); Yb (5)], were prepared by hydro- and solvothermal reactions of lanthanide chlorides with itaconic acid (H2IA) and 1,10-phenanthroline (phen), and structurally characterized by single crystal X-ray diffraction. 1 Comprises 1-D double-chains that are further assembled to a 3-D supramolecular structure via hydrogen bonds and π–π stacks between phen molecules. 2 and 3 have 2-D infinite networks which are further constructed to form 3-D supramolecular architectures with 1-D channels by π–π aromatic interactions. 4 and 5 have 2-D layer structures consisting of three types of rings which are further architectured to form 3-D supramolecular structures by C–H⋯O hydrogen bonds. The H2IA ligands are all completely deprotonated and exhibit tetra-, penta-, and hexadentate coordination modes in the titled complexes. The high-resolution emission spectrum of 2 shows only one Eu3+ ion site in 2, which is in agreement with the result of X-ray diffraction. And the magnetic property and the thermal stability of 2 were also investigated." @default.
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- W2029649448 date "2005-06-01" @default.
- W2029649448 modified "2023-10-14" @default.
- W2029649448 title "Structural change of supramolecular coordination polymers of itaconic acid and 1,10-phenanthroline along lanthanide series" @default.
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- W2029649448 doi "https://doi.org/10.1016/j.ica.2005.03.015" @default.
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