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- W2029655083 abstract "Die Synthesen der diastereomeren Homofulvene 6-Deuterio-endo- und -exo-6-isopropyl-1,2,3,5- tetramethyl-4-methylenbicyclo[3.1.0]hex-2-en ([6-D]-endo-1b und [6-D]-exo-1b) werden beschrieben. Beide Verbindungen isomerisieren nach Anregung in den S1-Zustand zu 6-Deuterio-6-isopropyl-1,2,3,4-tetramethyl-5-methylen-1,3-cyclohexadien ([6-D]-2b). Ein Mechanismus für den Verlauf dieser Photo-Isomerisierung wird vorgeschlagen. An Investigation of 6-Deuterio-endo-and-exo-6-isopropyl-1,2,3,5-tetramethyl-4-methylenebicyclo[3.1.0]hex-2-ene on the Mechanism of the Singlet Excited Photo-Isomerization of the Homofulvene System Synthese of the diastereomeric homofulvenes 6-deuterio-endo- and -exo-6-isopropyl-1,2,3,5-tetramethyl-4-methylenebicyclo[3.1.0]hex-2-ene ([6-D]-endo-1 b and [6-D]-exo-1 b) are reported. Following excitation to the S1-state both compounds isomerize to 6-deuterio-6-isopropyl-1,2,3,5-tetramethyl-5-methylene-1,3-cyclohexadiene. A mechanism for the reaction sequence is suggested." @default.
- W2029655083 created "2016-06-24" @default.
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- W2029655083 title "Eine Untersuchung an 6‐Deuterio‐ <i>endo</i> ‐ und‐ <i>exo</i> ‐6‐isopropyl‐1,2,3,5‐tetramethyl‐4‐methylenbicyclo[3.1.0]hex‐2‐en über den Mechanismus der Singulett‐angeregten Photo‐Isomerisierung des Homofulven‐Systems" @default.
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- W2029655083 doi "https://doi.org/10.1002/cber.19851180710" @default.
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