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• W2029658420 endingPage "2078" @default.
• W2029658420 startingPage "2068" @default.
• W2029658420 abstract "Two 3D isostructures of {[M5(atrz)6(μ 2-O)](NO3)2(H2O)6}∞ (1 · M(NO3)2(H2O)6; M = ZnII, CoII; atrz = 3-amino-1H-1,2,4-triazole anion) have been obtained via hydrothermal techniques. Both crystallize in the cubic space group with a = 15.0416(2) Å, V = 3403.16(8) Å3, Z = 4 for 1 · Zn and a = 15.046(2) Å, V = 3406.1(9) Å3, Z = 4 for 1 · Co. The framework of 1 consists of [M3(atrz)6] (M = ZnII, CoII), trinuclear linear MII building block, linked through tetrahedral sites of [MN3O], extending to a 3D structure containing numerous cages in which 2n NO3– and 6n H2O are locked. In 1, MII ions show octahedral and tetrahedral coordination geometries and atrz are three-connected nodes. The polymers were characterized by single-crystal X-ray diffraction, thermogravimetric analysis (TGA), elemental analysis and infrared spectroscopy." @default.
• W2029658420 created "2016-06-24" @default.
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• W2029658420 date "2008-07-10" @default.
• W2029658420 modified "2023-09-26" @default.
• W2029658420 title "Inclusion cages constructed from trinuclear linear Zn^II/Co^II building blocks" @default.
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• W2029658420 doi "https://doi.org/10.1080/00958970701866135" @default.
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