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- W2029659047 abstract "Abstract A route to an approximate value for the bending force constant k β associated with the angular oscillation β of the B subunit in a weakly bound AB dimer (A, symmetric top; B, linear molecule) from gas-phase nuclear quadrupole coupling constants is examined. The k β calculated in this way are sensitive to errors in the experimental nuclear quadrupole coupling constants and to the values used for the “vibrationless” equilibrium nuclear quadrupole coupling constants. The results for a number of dimers show k β to be comparable in magnitude to that for the corresponding motion of the A subunit ( k α ) obtained previously from centrifugal distortion constants." @default.
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- W2029659047 title "Bending force constants for weakly bound dimers AB (A, symmetric top; B, linear molecule) from gas-phase nuclear quadrupole coupling constants" @default.
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- W2029659047 doi "https://doi.org/10.1016/0022-2860(96)09236-8" @default.
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