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- W2029665730 abstract "The objective of this work is the study of a reactional pathway characteristic of an electrodeposition process with adsorption. It involves five limiting steps. The determination of the impedance expression corresponding to this mechanism leads us to give an electrical equivalent circuit. The expression of the real part of the diffusion impedance can be negative when there is adsorption of a competitive species at the electrode. In this case, the shape of the impedance diagram is quite special because the real part of the impedance leads to negative values. The experimental diagrams were realized during the reduction of Te(IV) into Te(0). These diagrams were simulated and the good agreement obtained between the experimental and calculated curves confirms the rate determining steps involved in the reactional pathway proposed." @default.
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- W2029665730 date "1993-10-01" @default.
- W2029665730 modified "2023-10-18" @default.
- W2029665730 title "Theoretical investigation of the electrochemical deposition of metal involving adsorption and desorption steps" @default.
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- W2029665730 doi "https://doi.org/10.1016/0013-4686(93)80338-z" @default.
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