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• W2029673006 abstract "A fluorine-containing polyacrylate copolymer emulsion was synthesized by a seed emulsion polymerization method, in which methyl methacrylate (MMA) and butyl acrylate (BA) were used as main monomers and hexafluorobutyl methacrylate (HFMA) as fluorine-containing monomer. The structure and properties were characterized by Fourier transform infrared spectrum (FT-IR), transmission electron microscopy (TEM), particle size analysis, X-ray photoelectron spectroscopy (XPS), contact angle (CA), differential scanning calorimetry (DSC) and thermogravimetry (TG) analysis. The FTIR and TEM results showed that HFMA was effectively involved in the emulsion copolymerization, and the formed emulsion particles had a core-shell structure and a narrow particle size distribution. XPS and CA analysis revealed that a gradient concentration of fluorine existed in the depth profile of fluorine-containing emulsion film which was richer in fluorine and more hydrophobic in one side. DSC and TG analysis also showed that a clear core-shell structure existed in the fluorine-containing emulsion particles, and their film showed higher thermal stability than that of fluorine-free emulsion." @default.
• W2029673006 created "2016-06-24" @default.
• W2029673006 creator A5015839168 @default.
• W2029673006 creator A5021318566 @default.
• W2029673006 date "2008-01-01" @default.
• W2029673006 modified "2023-09-24" @default.
• W2029673006 title "Synthesis and Characterization of Fluorine-containing Polyacrylate Emulsion with Core-Shell Structure" @default.
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• W2029673006 doi "https://doi.org/10.1016/s1004-9541(08)60131-7" @default.
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