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- W2029681982 abstract "The effect of solvent polarity on the observed hyperfine coupling constants of nitroxide radicals has been investigated both in the presence of and in the absence of hydrogen donors. With inert solvents, the observed hyperfine coupling constant increases linearly with (ϵ -̊ 1)/(ϵ + 1). With hydrogen donors, the observed hyperfine coupling constants are much greater, in part because of the dielectric constant of the medium and in part because of the equilibrium between free and complexed radicals. Correcting for the effect of the dielectric constant of the medium on the observed hyperfine coupling constants in the determination of association constants of transient complexes is illustrated for the donors C3H7OH, C4H9OH, CF3CH2OH, C6H5OH, (CH3)3COH, and CHCl3. Association constants for these donors with TMPO at room temperature in benzene are found to be in the range from 0.68 to 2.04 M−1." @default.
- W2029681982 created "2016-06-24" @default.
- W2029681982 creator A5003658948 @default.
- W2029681982 creator A5064064531 @default.
- W2029681982 date "1987-06-01" @default.
- W2029681982 modified "2023-09-25" @default.
- W2029681982 title "Medium effects on ESR spectra in studies of hydrogen-bonded transient solvent-solute complexes" @default.
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- W2029681982 doi "https://doi.org/10.1016/0022-2364(87)90226-5" @default.
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