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- W2029687545 abstract "The use of a silicon stereocontrol element in cyclobutanol and cyclopentanol-forming cyclizations mediated by SmI(2) results in excellent diastereocontrol. The C-Si bond in the products of cyclization provides a versatile handle for further manipulation. An asymmetric route to cyclization substrates involving copper-catalyzed silyl transfer has also been developed." @default.
- W2029687545 created "2016-06-24" @default.
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- W2029687545 date "2010-11-04" @default.
- W2029687545 modified "2023-09-23" @default.
- W2029687545 title "SmI2-Mediated Radical Cyclizations Directed by a C−Si Bond" @default.
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- W2029687545 doi "https://doi.org/10.1021/ol102278c" @default.
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