FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2029689932> ?p ?o ?g. }

• W2029689932 endingPage "6486" @default.
• W2029689932 startingPage "6477" @default.
• W2029689932 abstract "We have studied the reaction of NO2 with BaO nanoparticles supported on an ordered Al2O3 thin film on NiAl(110). Combining chemical analysis by X-ray photoelectron spectroscopy (XPS) and vibrational spectroscopy by infrared reflection absorption spectroscopy (IRAS), performed in combination with molecular beam (MB) techniques, the sequence of appearance of various nitrogen−oxo surface intermediates and their spectral properties are identified. The initial intermediates at 300 K are surface nitrites (NO2-), which are preferentially oriented parallel to the surface. Whereas formation of nitrites is rapid even at 300 K, conversion of nitrites into surface nitrates (NO3-) occurs at a very low rate. After surface nitrate formation, no further reaction is observed. At higher temperature (500 K), conversion into surface nitrates is more facile and is followed by formation of ionic nitrates. All three nitrogen−oxo species can be clearly identified via their characteristic vibrational spectra. No spectroscopic evidence for the formation of other NOx-derived surface species is found under the reaction conditions applied in this study. The results suggest that (i) conversion of the surface nitrite into the surface nitrate and (ii) formation of the ionic nitrate are the rate-controlling steps in the storage process." @default.
• W2029689932 created "2016-06-24" @default.
• W2029689932 creator A5001347696 @default.
• W2029689932 creator A5008464541 @default.
• W2029689932 creator A5018206907 @default.
• W2029689932 creator A5035111702 @default.
• W2029689932 creator A5035522337 @default.
• W2029689932 creator A5040005623 @default.
• W2029689932 creator A5041705912 @default.
• W2029689932 creator A5072121421 @default.
• W2029689932 date "2008-03-29" @default.
• W2029689932 modified "2023-09-25" @default.
• W2029689932 title "Modeling NO<i>_x</i> Storage Materials: On the Formation of Surface Nitrites and Nitrates and Their Identification by Vibrational Spectroscopy" @default.
• W2029689932 cites W1493062497 @default.
• W2029689932 cites W1643436027 @default.
• W2029689932 cites W1965124778 @default.
• W2029689932 cites W1965219631 @default.
• W2029689932 cites W1965841478 @default.
• W2029689932 cites W1968973004 @default.
• W2029689932 cites W1972005566 @default.
• W2029689932 cites W1974516579 @default.
• W2029689932 cites W1980953390 @default.
• W2029689932 cites W1981321518 @default.
• W2029689932 cites W1981741618 @default.
• W2029689932 cites W1983491187 @default.
• W2029689932 cites W1988628988 @default.
• W2029689932 cites W1989923395 @default.
• W2029689932 cites W1992649146 @default.
• W2029689932 cites W1996839316 @default.
• W2029689932 cites W2003286256 @default.
• W2029689932 cites W2004066338 @default.
• W2029689932 cites W2004660849 @default.
• W2029689932 cites W2004740050 @default.
• W2029689932 cites W2010154632 @default.
• W2029689932 cites W2012200882 @default.
• W2029689932 cites W2015565142 @default.
• W2029689932 cites W2018449651 @default.
• W2029689932 cites W2024908230 @default.
• W2029689932 cites W2025487691 @default.
• W2029689932 cites W2026130053 @default.
• W2029689932 cites W2036089712 @default.
• W2029689932 cites W2038473518 @default.
• W2029689932 cites W2038621121 @default.
• W2029689932 cites W2039228238 @default.
• W2029689932 cites W2040352842 @default.
• W2029689932 cites W2040663003 @default.
• W2029689932 cites W2041526874 @default.
• W2029689932 cites W2042003689 @default.
• W2029689932 cites W2042032167 @default.
• W2029689932 cites W2047962693 @default.
• W2029689932 cites W2050393848 @default.
• W2029689932 cites W2055162482 @default.
• W2029689932 cites W2055889792 @default.
• W2029689932 cites W2066468902 @default.
• W2029689932 cites W2068804685 @default.
• W2029689932 cites W2070329158 @default.
• W2029689932 cites W2071139371 @default.
• W2029689932 cites W2075440249 @default.
• W2029689932 cites W2078341424 @default.
• W2029689932 cites W2083170028 @default.
• W2029689932 cites W2085256702 @default.
• W2029689932 cites W2093947601 @default.
• W2029689932 cites W2094469059 @default.
• W2029689932 cites W2102061762 @default.
• W2029689932 cites W2102381420 @default.
• W2029689932 cites W2122688016 @default.
• W2029689932 cites W2123815867 @default.
• W2029689932 cites W2124108446 @default.
• W2029689932 cites W2128431455 @default.
• W2029689932 cites W2131604400 @default.
• W2029689932 cites W2137255664 @default.
• W2029689932 cites W2142412171 @default.
• W2029689932 cites W2142806832 @default.
• W2029689932 cites W2168277502 @default.
• W2029689932 cites W40746870 @default.
• W2029689932 doi "https://doi.org/10.1021/jp710994d" @default.
• W2029689932 hasPublicationYear "2008" @default.
• W2029689932 type Work @default.
• W2029689932 sameAs 2029689932 @default.
• W2029689932 citedByCount "34" @default.
• W2029689932 countsByYear W20296899322012 @default.
• W2029689932 countsByYear W20296899322013 @default.
• W2029689932 countsByYear W20296899322014 @default.
• W2029689932 countsByYear W20296899322015 @default.
• W2029689932 countsByYear W20296899322018 @default.
• W2029689932 countsByYear W20296899322019 @default.
• W2029689932 countsByYear W20296899322020 @default.
• W2029689932 countsByYear W20296899322023 @default.
• W2029689932 crossrefType "journal-article" @default.
• W2029689932 hasAuthorship W2029689932A5001347696 @default.
• W2029689932 hasAuthorship W2029689932A5008464541 @default.
• W2029689932 hasAuthorship W2029689932A5018206907 @default.
• W2029689932 hasAuthorship W2029689932A5035111702 @default.
• W2029689932 hasAuthorship W2029689932A5035522337 @default.
• W2029689932 hasAuthorship W2029689932A5040005623 @default.
• W2029689932 hasAuthorship W2029689932A5041705912 @default.
• W2029689932 hasAuthorship W2029689932A5072121421 @default.
• W2029689932 hasConcept C105923489 @default.

• next