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- W2029690114 abstract "The hydrogenation of CO under pressure over a Rh/ThO2 catalyst leads to a mixture of hydrocarbons and alcohols. The addition of propene to the CO + 2H2 mixture enhances the production of n- and isobutanols but not of C4 hydrocarbons. This suggests that a CO insertion into the RhC bond of an alkyl surface species constitutes the termination step towards oxygen-containing compounds, but does not contribute significantly to the hydrocarbon chain growth process. The n/iso ratio for butanols increases during the first hours of the CO + H2 reaction; this is attributed to steric effects of adsorbed hydrocarbons which would favour an n-propyl relatively to an isopropyl intermediate. As ethanol does not appear to be formed subsequently to methanol, the alcohols homologation reaction is not a major process on the Rh/ThO2 catalyst. Isopropanol becomes detectable after about 2 h of reaction and its production increases with time; it could be formed by the hydrogenation of acetone resulting from the decomposition of acetate species bonded to thoria." @default.
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- W2029690114 date "1986-07-01" @default.
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- W2029690114 title "Alcohols formation through Rh/ThO2 catalyzed hydrogenation of carbon monoxide" @default.
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- W2029690114 doi "https://doi.org/10.1016/s0166-9834(00)81269-5" @default.
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