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• W2029694292 abstract "Eleven isotopic species of methylenimine have been prepared by the mercury-arc photolysis of methyl azide isolated in argon, nitrogen, and carbon dioxide matrices at 4 and at 14 K. Sufficient concentrations of methylenimine were obtained for identification of all of the vibrational fundamentals except the NH stretching mode. Using a recent ab initio structural calculation for this molecule, it has been possible to derive a set of valence-force potential constants which provide a satisfactory fit to all of the infrared spectroscopic data. The magnitude of the carbon-nitrogen stretching force constant is appropriate for a double bond. The temperature dependence of the thermodynamic properties of methylenimine has also been calculated." @default.
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• W2029694292 date "1975-06-01" @default.
• W2029694292 modified "2023-10-10" @default.
• W2029694292 title "The infrared spectrum of methylenimine" @default.
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• W2029694292 doi "https://doi.org/10.1016/0022-2852(75)90122-8" @default.
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