FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2029705038> ?p ?o ?g. }

• W2029705038 endingPage "353" @default.
• W2029705038 startingPage "345" @default.
• W2029705038 abstract "The synthesis of boron-containing polysilylcarbodi-imides of general type {B[C2H4(R)SiNCN]3}n [6a R = CH3, 6b R = H, 6c R = (NCN)0.5] by different reactions and their thermal behaviour are discussed. The title compounds 6a–6c can be obtained by a hydroboration reaction of BH3*S(CH3)2 (5) with the vinyl-substituted polysilylcarbodi-imides [(H2C=CH)(R)SiNCN]n [3a R = CH3, 3b R = H, 3c R = (NCN)0.5], which themselves are accessible from the reaction of the vinyl-substituted chlorosilanes (H2C=CH)(R)SiCl2 (1a R = CH3, lb R = H, 1c R = Cl) with stoichiometric amounts of H2N-C≡N (2). Furthermore, a method for the synthesis of compounds 6a–6c is given by treatment of compounds 1a–1c with (H3C)3SiN=C=NSi(CH3)3 (4). An alternative reaction sequence, which finally leads to compounds 6a–6c is the hydroboration of the monomeric vinyl-substituted chlorosilanes 1a–1c with BH3 * S(CH3)2 (5) to yield the chlorosilylethylboranes B[C2H4(R)SiCl2]3 (7a R = CH3, 7b R = H, 7c R = Cl) at first. Treatment of compounds 7a–7c with (H3C)3SiN=C=NSi(CH3)3 (4), even with or without solvent, stoichiometrically or with excess 4, produces the hydroborated polysilylcarbodi-imides 6a–6c. The thermogravimetric behaviour of the polysilycarbodi-imides 3a–3c as well as the boron-containing polymers 6a–6c have been determined by simultaneous TGA (20–1100°C, argon, heating rate 2 Kmin−1). The ceramic yields of the polymers are in the range of 53–73%, depending on the structure and the composition of the polymers applied." @default.
• W2029705038 created "2016-06-24" @default.
• W2029705038 creator A5015323698 @default.
• W2029705038 creator A5031419413 @default.
• W2029705038 creator A5041034055 @default.
• W2029705038 creator A5054501918 @default.
• W2029705038 creator A5064293078 @default.
• W2029705038 creator A5079388529 @default.
• W2029705038 date "1997-08-01" @default.
• W2029705038 modified "2023-10-14" @default.
• W2029705038 title "Boron-containing polysilylcarbodi-imides: A new class of molecular precursors for Si-B-C-N ceramics" @default.
• W2029705038 cites W1611259729 @default.
• W2029705038 cites W1968837950 @default.
• W2029705038 cites W1973773373 @default.
• W2029705038 cites W1976993995 @default.
• W2029705038 cites W1988168939 @default.
• W2029705038 cites W1991289402 @default.
• W2029705038 cites W1994993502 @default.
• W2029705038 cites W2000807575 @default.
• W2029705038 cites W2012619538 @default.
• W2029705038 cites W2016379499 @default.
• W2029705038 cites W2018315977 @default.
• W2029705038 cites W2042367586 @default.
• W2029705038 cites W2044675492 @default.
• W2029705038 cites W2045564336 @default.
• W2029705038 cites W2052874452 @default.
• W2029705038 cites W2054692627 @default.
• W2029705038 cites W2068778618 @default.
• W2029705038 cites W2078017447 @default.
• W2029705038 cites W2078026041 @default.
• W2029705038 cites W2078159644 @default.
• W2029705038 cites W2081975827 @default.
• W2029705038 cites W2082867611 @default.
• W2029705038 cites W2083565541 @default.
• W2029705038 cites W2085297381 @default.
• W2029705038 cites W2085325190 @default.
• W2029705038 cites W2091455817 @default.
• W2029705038 cites W2100130011 @default.
• W2029705038 cites W2107491498 @default.
• W2029705038 cites W2124661266 @default.
• W2029705038 cites W2139723991 @default.
• W2029705038 cites W2165936788 @default.
• W2029705038 cites W227459124 @default.
• W2029705038 cites W2950873337 @default.
• W2029705038 doi "https://doi.org/10.1016/s0022-328x(97)00085-5" @default.
• W2029705038 hasPublicationYear "1997" @default.
• W2029705038 type Work @default.
• W2029705038 sameAs 2029705038 @default.
• W2029705038 citedByCount "72" @default.
• W2029705038 countsByYear W20297050382012 @default.
• W2029705038 countsByYear W20297050382013 @default.
• W2029705038 countsByYear W20297050382014 @default.
• W2029705038 countsByYear W20297050382015 @default.
• W2029705038 countsByYear W20297050382016 @default.
• W2029705038 countsByYear W20297050382017 @default.
• W2029705038 countsByYear W20297050382018 @default.
• W2029705038 countsByYear W20297050382019 @default.
• W2029705038 countsByYear W20297050382020 @default.
• W2029705038 countsByYear W20297050382022 @default.
• W2029705038 countsByYear W20297050382023 @default.
• W2029705038 crossrefType "journal-article" @default.
• W2029705038 hasAuthorship W2029705038A5015323698 @default.
• W2029705038 hasAuthorship W2029705038A5031419413 @default.
• W2029705038 hasAuthorship W2029705038A5041034055 @default.
• W2029705038 hasAuthorship W2029705038A5054501918 @default.
• W2029705038 hasAuthorship W2029705038A5064293078 @default.
• W2029705038 hasAuthorship W2029705038A5079388529 @default.
• W2029705038 hasConcept C134121241 @default.
• W2029705038 hasConcept C144082473 @default.
• W2029705038 hasConcept C155647269 @default.
• W2029705038 hasConcept C161790260 @default.
• W2029705038 hasConcept C166940927 @default.
• W2029705038 hasConcept C178790620 @default.
• W2029705038 hasConcept C185592680 @default.
• W2029705038 hasConcept C188027245 @default.
• W2029705038 hasConcept C191897082 @default.
• W2029705038 hasConcept C192562407 @default.
• W2029705038 hasConcept C196306401 @default.
• W2029705038 hasConcept C2780471494 @default.
• W2029705038 hasConcept C501308230 @default.
• W2029705038 hasConcept C521977710 @default.
• W2029705038 hasConcept C60100273 @default.
• W2029705038 hasConceptScore W2029705038C134121241 @default.
• W2029705038 hasConceptScore W2029705038C144082473 @default.
• W2029705038 hasConceptScore W2029705038C155647269 @default.
• W2029705038 hasConceptScore W2029705038C161790260 @default.
• W2029705038 hasConceptScore W2029705038C166940927 @default.
• W2029705038 hasConceptScore W2029705038C178790620 @default.
• W2029705038 hasConceptScore W2029705038C185592680 @default.
• W2029705038 hasConceptScore W2029705038C188027245 @default.
• W2029705038 hasConceptScore W2029705038C191897082 @default.
• W2029705038 hasConceptScore W2029705038C192562407 @default.
• W2029705038 hasConceptScore W2029705038C196306401 @default.
• W2029705038 hasConceptScore W2029705038C2780471494 @default.
• W2029705038 hasConceptScore W2029705038C501308230 @default.
• W2029705038 hasConceptScore W2029705038C521977710 @default.
• W2029705038 hasConceptScore W2029705038C60100273 @default.
• W2029705038 hasIssue "1-2" @default.

• next