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- W2029709145 abstract "The reaction of the dianion [Os4H2(CO)11]2− with two equivalents of Au2(DPPM)Cl2(DPPM = Ph2PCH2PPh2), in the presence of T1[PF6], affords a digold species which upon treatment with NEt3 gives the neutral cluster [Os4H2(CO)11Au2(DPPM)2]. This cluster has been characterised by 1H and 31P NMR spectroscopy, mass spectrometry and X-ray crystallography. The metal core consists of an Os4 tetrahedron, one face of which is capped by three Au atoms while the fourth Au atom caps an OsAu2 face." @default.
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- W2029709145 date "1997-05-01" @default.
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- W2029709145 title "Synthesis and structural characterisation of [Os4H2(CO)11Au2(DPPM)2]: The first cluster with an Os4Au4 core" @default.
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- W2029709145 doi "https://doi.org/10.1016/s0022-328x(96)06762-9" @default.
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