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- W2029710643 abstract "The octupolar metal complexes [Zn(bpy)(L)] (1), [Cd(bpy)(L)] (2), [Hg(bpy)(L)] (3) (bpy = 2,2′-bipyridyl, L = 4-dimethylamino-α-cyanocinnamic acid) have been synthesized. The third-order nonlinear optical properties of complexes were studied using Z-scan technique at 532 nm with nanosecond laser pulses. The complexes show optical limiting behavior. The values of the effective two-photon absorption (2PA) coefficients (β), third-order nonlinear susceptibilities (χ(3)) and two-photon absorption cross sections (σ2) are calculated. Results show, lewis acidity of metal center and molecular symmetry are two important factors for observed large TPA cross-section of metal complexes." @default.
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- W2029710643 date "2012-07-01" @default.
- W2029710643 modified "2023-10-18" @default.
- W2029710643 title "Octupolar metal complexes for third order nonlinear optical studies" @default.
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- W2029710643 doi "https://doi.org/10.1016/j.cplett.2012.06.022" @default.
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