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- W2029734493 abstract "Abstract Chronoamperometric, chronopotentiometric and chronovoltammetric experiments were performed for the reduction of zinc ions on hanging gold amalgam drop electrodes when the zinc ion concentration in the solution was considerably higher than the concentration of gold in the amalgam. The formation of a pre-peak was observed which corresponds to electroreduction of zinc(II) to the intermetallic compound AuZn in mercury. Chronovoltammetric experiments may be utilized for analytical determinations of the gold concentrations in homogeneous amalgams. Analysis of the chronoamperometric experiments enabled the determination of the diffusion coefficient of gold in mercury which was found to be (8.5±0.4)×10−6cm2 s−1 at 298.2 K." @default.
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- W2029734493 date "1977-10-01" @default.
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- W2029734493 title "Determination of diffusion coefficient and concentration of gold in mercury based on the pre-peak formation in the reduction of zinc(II) at hanging gold amalgam drop electrodes" @default.
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- W2029734493 doi "https://doi.org/10.1016/s0022-0728(77)80507-x" @default.
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