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- W2029742010 abstract "A manganese(II) complex with N,N′-bis(carboxymethyl)dithiooxamide (H4GLYDTO), [Mn(H2GLYDTO)(H2O)2]n, has been synthesized and characterized by elemental analysis and thermogravimetric analysis, as well as by infrared, electronic and EPR spectroscopy and magnetic susceptibility measurements. The crystal and molecular structure of this complex was determined by single-crystal X-ray structure analysis. The compound shows a 3D porous framework with alternate left- and right-handed helical channels where the manganese(II) ions have an octahedral environment. Variable temperature magnetic measurements reveal the existence of very weak antiferromagnetic interactions through the syn-anti carboxylate bridge, with an exchange parameter of J/k = -0.12 K. © 2009 Elsevier Ltd. All rights reserved." @default.
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- W2029742010 date "2009-03-01" @default.
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- W2029742010 title "A manganese(II) coordination polymer with a 3D porous structure: Synthesis, structure, and spectroscopic and magnetic behaviour" @default.
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- W2029742010 doi "https://doi.org/10.1016/j.poly.2008.12.030" @default.
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