Matches in SemOpenAlex for { <https://semopenalex.org/work/W2029772790> ?p ?o ?g. }
- W2029772790 endingPage "41" @default.
- W2029772790 startingPage "21" @default.
- W2029772790 abstract "Abstract Unambiguous 13C assignments have been obtained, using 2D-n.m.r. techniques, for several glycosyl azides, 6-deoxyglycosyl azides, 2-acylamino-2-deoxyglycosyl azides, and some 2- and 3-azido monosaccharide derivatives. For non-anomeric CH bonds the 1JC,He values are 4–9 Hz larger than the 1JC,Ha values. A substituent (hydroxyl, acetoxyl, alkoxyl, azido, etc.) in 1,3-diaxial relationship with Ha significantly increases the value of 1JC,Ha. Bond-angle distortions in the fused-ring bicyclic systems of some isopropylidene derivatives result in 1JC,Ha values being larger than 1JC,He values. Electronic and steric effects of substituents at non-anomeric carbons may alter the 1JC,H values for anomeric carbons to such an extent that they may no longer be useful for diagnosing anomeric configuration. Bond-angle deformations also influence the 13C chemical shift differences in α- and β-anomers at C-5 and, to a lesser extent, at C-3." @default.
- W2029772790 created "2016-06-24" @default.
- W2029772790 creator A5031504546 @default.
- W2029772790 creator A5041318802 @default.
- W2029772790 date "1985-11-01" @default.
- W2029772790 modified "2023-10-18" @default.
- W2029772790 title "A 13C-N.M.R. investigation of glycosyl azides and other azido sugars: Stereochemical influences on the one-bond 13C-1H coupling constants" @default.
- W2029772790 cites W1560726277 @default.
- W2029772790 cites W1592318401 @default.
- W2029772790 cites W1791612812 @default.
- W2029772790 cites W1964316590 @default.
- W2029772790 cites W1965137757 @default.
- W2029772790 cites W1965774522 @default.
- W2029772790 cites W1968279397 @default.
- W2029772790 cites W1969160162 @default.
- W2029772790 cites W1971785989 @default.
- W2029772790 cites W1974435146 @default.
- W2029772790 cites W1976288666 @default.
- W2029772790 cites W1976726243 @default.
- W2029772790 cites W1980995572 @default.
- W2029772790 cites W1983003284 @default.
- W2029772790 cites W1991204682 @default.
- W2029772790 cites W1995671956 @default.
- W2029772790 cites W2008903965 @default.
- W2029772790 cites W2009472011 @default.
- W2029772790 cites W2009802623 @default.
- W2029772790 cites W2015193046 @default.
- W2029772790 cites W2015536749 @default.
- W2029772790 cites W2016778686 @default.
- W2029772790 cites W2022476771 @default.
- W2029772790 cites W2026751039 @default.
- W2029772790 cites W2029798963 @default.
- W2029772790 cites W2034886201 @default.
- W2029772790 cites W2040914439 @default.
- W2029772790 cites W2042570117 @default.
- W2029772790 cites W2043007816 @default.
- W2029772790 cites W2045412891 @default.
- W2029772790 cites W2045832896 @default.
- W2029772790 cites W2053872292 @default.
- W2029772790 cites W2054371924 @default.
- W2029772790 cites W2055290787 @default.
- W2029772790 cites W2055433334 @default.
- W2029772790 cites W2059642036 @default.
- W2029772790 cites W2060678631 @default.
- W2029772790 cites W2068597171 @default.
- W2029772790 cites W2070408139 @default.
- W2029772790 cites W2070764306 @default.
- W2029772790 cites W2071031832 @default.
- W2029772790 cites W2077974464 @default.
- W2029772790 cites W2084225313 @default.
- W2029772790 cites W2086856750 @default.
- W2029772790 cites W2093306193 @default.
- W2029772790 cites W2094929821 @default.
- W2029772790 cites W2107681579 @default.
- W2029772790 cites W2153746240 @default.
- W2029772790 cites W217768497 @default.
- W2029772790 cites W2313522033 @default.
- W2029772790 cites W2315289476 @default.
- W2029772790 cites W2316251386 @default.
- W2029772790 cites W2319333800 @default.
- W2029772790 cites W2323064901 @default.
- W2029772790 cites W2327346648 @default.
- W2029772790 cites W2400891287 @default.
- W2029772790 cites W3005093480 @default.
- W2029772790 cites W3206118840 @default.
- W2029772790 doi "https://doi.org/10.1016/s0008-6215(00)90692-x" @default.
- W2029772790 hasPublicationYear "1985" @default.
- W2029772790 type Work @default.
- W2029772790 sameAs 2029772790 @default.
- W2029772790 citedByCount "73" @default.
- W2029772790 countsByYear W20297727902012 @default.
- W2029772790 countsByYear W20297727902013 @default.
- W2029772790 countsByYear W20297727902014 @default.
- W2029772790 countsByYear W20297727902015 @default.
- W2029772790 countsByYear W20297727902017 @default.
- W2029772790 countsByYear W20297727902018 @default.
- W2029772790 countsByYear W20297727902021 @default.
- W2029772790 countsByYear W20297727902022 @default.
- W2029772790 countsByYear W20297727902023 @default.
- W2029772790 crossrefType "journal-article" @default.
- W2029772790 hasAuthorship W2029772790A5031504546 @default.
- W2029772790 hasAuthorship W2029772790A5041318802 @default.
- W2029772790 hasConcept C109214941 @default.
- W2029772790 hasConcept C121332964 @default.
- W2029772790 hasConcept C127413603 @default.
- W2029772790 hasConcept C131584629 @default.
- W2029772790 hasConcept C147597530 @default.
- W2029772790 hasConcept C155647269 @default.
- W2029772790 hasConcept C163111631 @default.
- W2029772790 hasConcept C178790620 @default.
- W2029772790 hasConcept C183276030 @default.
- W2029772790 hasConcept C185592680 @default.
- W2029772790 hasConcept C2780906977 @default.
- W2029772790 hasConcept C2780997848 @default.
- W2029772790 hasConcept C71240020 @default.
- W2029772790 hasConcept C78519656 @default.
- W2029772790 hasConceptScore W2029772790C109214941 @default.
- W2029772790 hasConceptScore W2029772790C121332964 @default.