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- W2029773681 abstract "The thioethers, S-(4-amino-2,4-dicarboxybutyl)cysteamine, S-(4-amino-2,4-dicarboxybutyl)cysteine and S-(4-amino-2,4-dicarboxybutyl)glutathione, were synthesized by a Michael addition between 4-methyleneglutamic acid and the respective thiol. In dilute aqueous solution, the reactions exhibit second order kinetics; glutathione reacts much slower than cysteine or cysteamine. The adducts were characterized chromatographically, electrophoretically, and by their infra-red and nuclear magnetic resonance spectra. None of these thioethers was detected in peanut plants (Arachis hypogaea L.), even though large amounts of 4-methyleneglutamic acid, its amide, and glutathione are synthesized during peanut germination." @default.
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- W2029773681 date "1982-04-01" @default.
- W2029773681 modified "2023-10-16" @default.
- W2029773681 title "Michael addition of thiols with 4-methyleneglutamic acid: Preparation of adducts, their properties and presence in peanuts" @default.
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- W2029773681 doi "https://doi.org/10.1016/0006-291x(82)90937-8" @default.
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