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• W2029776867 startingPage "357" @default.
• W2029776867 abstract "Proton transfer in the chelated form of malonaldehyde is commonly supposed to occur between two tautomers, across a transition state involving changes of the chemical bonding. We show that this view is in conflict with rotational spectra. The molecule is better thought of as a superposition of indistinguishable and non-separable Cs tautomers and proton tunneling is totally decoupled from the other degrees of freedom. Double minimum potential functions are determined from experiments and ab initio calculations." @default.
• W2029776867 created "2016-06-24" @default.
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• W2029776867 date "2005-11-01" @default.
• W2029776867 modified "2023-09-30" @default.
• W2029776867 title "Proton transfer in malonaldehyde: From reaction path to Schrödinger’s Cat" @default.
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• W2029776867 doi "https://doi.org/10.1016/j.cplett.2005.08.147" @default.
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