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- W2029791379 abstract "The tentacle-bearing ferrocenes [Fe{R4C5SiMe2}(OCH2CH2)nOMe2] (4a: R = H, n = 2; 4b: R = Me, n = 2; 4c: R = H, n = 3; 4d: R = Me, n = 3) and [Fe{Me4C5(CH2)3(OCH2CH2})3OME2] (5) act as podands for alkali metal cations; 4b, 4d, and 5 are much better podands than 4a and 4c. Compound 5 and [(C5H5)Fe{Me4C5(CH2)3(OCH2CH2)3OMe}] (8) are oxidized to 5+ [PF6]− and 8+ [PF6]−, respectively, which both show no tendency to crystallize. The cobaltocenium species [Co{Me4C5(CH2)3(OCH2CH2})3OMe-2]+ [PF6]− (11+ [PF6]−) is a selective podand, which prefers potassium over lithium cations; its potassium podate 11+ [PF6]− ∗ K+[PF6]− is the first example of a crystalline oligoethylene glycol ether podate, whose crystallinity does not rely on the rigid end-group principle." @default.
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- W2029791379 date "1997-01-01" @default.
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- W2029791379 title "Organometallic compounds as complexing agents: a rare example of a crystalline alkali metal podate" @default.
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- W2029791379 doi "https://doi.org/10.1016/s0277-5387(96)00438-x" @default.
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