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- W2029794101 abstract "In this paper we apply the theory of nonadiabatic multiphonon group transfer processes to describe the low temperature recombination reaction between CO and hemoglobin (CO–Hb) and between CO and carboxylmethyl cytochrome c (CO–cmcytc). The CO–Hb recombination is accompanied by an electronic transition from an S=2 high spin ‘‘free’’ state to an S=0 low open ‘‘bound’’ state, with the iron heme moving from a domed‐type structure into a planar structure, while the characteristic low frequency of relevant vibration mode(s) involving the heme iron coupled to the protein (〈ω〉∼50 cm−1). The CO‐cmcytc recombination characterized by an electronic transition from an S=1 spin free state to an S=0 bound state, with the iron heme ring staying planar and configurational frequencies prevail for a high‐frequency (ωc∼400 cm−1) in‐plane iron‐porphyrin vibrational mode. The distinct electronic and nuclear parameters for these two recombination processes account for the large difference in the onset of the temperature dependent rate for the CO–Hb (10 K) and for the CO–cmcytc (40 K) systems, as well as for the five orders of magnitude increase in the low‐temperature, temperature independent tunneling rate constant for CO–cmcytc relative to the CO–Hb recombination process." @default.
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- W2029794101 date "1985-11-01" @default.
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- W2029794101 title "The dynamics of carbon monoxide binding to hemoglobin and to cytochrome" @default.
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- W2029794101 doi "https://doi.org/10.1063/1.449065" @default.
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