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• W2029796162 abstract "The fluorine incorporation into HfO2 with oxygen vacancies has been investigated using first principles calculations. The authors show that atomic fluorine can efficiently passivate the neutral oxygen vacancy with excess energies of 4.98 and 4.39eV for threefold- and fourfold-coordinated oxygen vacancy sites, respectively. The introduction of fluorine elevates the vacancy induced state into conduction band by transferring the neutral vacancy state to positively charged state, and thus removes the gap state which causes trap-assisted tunneling. The HfO2 band gap is not narrowed after fluorine incorporation." @default.
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• W2029796162 date "2006-10-09" @default.
• W2029796162 modified "2023-10-16" @default.
• W2029796162 title "First principles calculations of oxygen vacancy passivation by fluorine in hafnium oxide" @default.
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• W2029796162 doi "https://doi.org/10.1063/1.2358121" @default.
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