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• W2029806661 abstract "Environmentally relevant abiotic reductants, such as zerovalent iron (ZVI) and minerals containing divalent iron (DVI), react predominantly by electron-transfer mechanisms with a variety of contaminant and probe compounds. Other reduction mechanisms involving activated forms of hydrogen (Hads or H–) have been suggested, but most evidence for these is only from systems containing noble metals that catalyze hydrogen activation (e.g., Pd). Here, 2-chlorophenylethanol and relatives of this aromatic halohydrin are used as probe compounds to show that ZVI can affect reduction by several novel pathways that are not observed with DVI minerals. These pathways include dechlorination by intramolecular nucleophilic substitution and epoxide ring opening by reduction. The former appears to be catalyzed by hydroxyl groups associated with oxides on actively corroding ZVI, and the latter can arise from hydride transfer (from NaBH4) or electron transfer (from ZVI)." @default.
• W2029806661 created "2016-06-24" @default.
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• W2029806661 date "2014-09-24" @default.
• W2029806661 modified "2023-10-17" @default.
• W2029806661 title "Novel Contaminant Transformation Pathways by Abiotic Reductants" @default.
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• W2029806661 doi "https://doi.org/10.1021/ez500268e" @default.
• W2029806661 hasPublicationYear "2014" @default.
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