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- W2029861292 abstract "Abstract Reaction of Ni(NCS) 2 (NH 3 ) 4 and [Pd(CN) 2 en] with the dipotassium salt of p -diethynylbenzene in liquid ammonia has given the homoleptic complexes K 2 [M( p -PDE) 2 ] (M Ni, Pd) ( p -PDE p -(CC) 2 C 6 H 4 ). Reduction of the Pd II complex with potassium in the same solvent gave the complex K 4 [Pd( p -PDE) 2 ]. These diamagnetic and polymeric complexes are very unstable to oxidation and hydrolysis. The reaction of the same dipotassium salt with MX 2 -(Ph 3 P) 2 complexes (M Ni, Pd; X halide) gave a new type of heteroleptic palladium (II) derivatives K 2 [Pd(CCC 6 H 4 CC) 2 (Ph 3 P) 2 ], but it was not possible to isolate the corresponding heteroleptic compound of Ni II . The observations are discussed in terms of a proposed mechanism for the reactions." @default.
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- W2029861292 date "1982-04-01" @default.
- W2029861292 modified "2023-10-03" @default.
- W2029861292 title "New nickel(II), palladium(II) and palladium(o) derivatives of p-diethynylbenzene" @default.
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- W2029861292 doi "https://doi.org/10.1016/s0022-328x(00)89121-4" @default.
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