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- W2029872906 abstract "Investigations on the Selectivity of the β-Scission of Alkyl Radicals, 11′1. – Selectivity of the β-Fragmentation of α-(Methoxycarbony1)alkyl RadicalsThe rate of β-scission of α-(Methoxycarbonyl)alkyl radicals 3 und 9, generated by addition of cycloalkyl radicals to appropriate methyl 2-methylenealkanoates 1 and methyl (E)-2-alkenoates 8, resp., has been measured relative to the hydrogen transfer from cycloalkanes. The rate of β-scission increases with increasing stability of the leaving radical R*, Polar effects reversing the stability sequence have also been observed, e. g. the stability sequence have also been observed, e. g. the more stable (methoxycarbonyl) methyl radical leaves more slowly than a less stable secondary alkyl radical." @default.
- W2029872906 created "2016-06-24" @default.
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- W2029872906 date "1990-04-01" @default.
- W2029872906 modified "2023-09-26" @default.
- W2029872906 title "Die β-Spaltung von α-(Methoxycarbonyl)alkyl-Radikalen" @default.
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- W2029872906 doi "https://doi.org/10.1002/cber.19901230437" @default.
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