FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2029884802> ?p ?o ?g. }

• W2029884802 endingPage "3629" @default.
• W2029884802 startingPage "3615" @default.
• W2029884802 abstract "A framework for applying rates of heterogeneous chemical reactions measured in the laboratory to small sulfuric acid aerosols found in the stratosphere is presented. The procedure for calculating the applicable reactive uptake coefficients using laboratory‐measured parameters is developed, the necessary laboratory‐measured quantities are discussed, and a set of equations for use in models are presented. This approach is demonstrated to be essential for obtaining uptake coefficients for the HOCl + HCl and ClONO 2 + HCl reactions applicable to the stratosphere. In these cases the laboratory‐measured uptake coefficients have to be substantially corrected for the small size of the atmospheric aerosol droplets. The measured uptake coefficients for N 2 O 5 + H 2 O and ClONO 2 + H 2 O as well as those for other heterogeneous reactions are discussed in the context of this model. Finally, the derived uptake coefficients were incorporated in a two‐dimensional dynamical and photochemical model thus for the first time the HCl reactions in sulfuric acid have been included. Substantial direct chlorine activation and consequent ozone destruction is shown to occur due to heterogeneous reactions involving HCl for volcanically perturbed aerosol conditions at high latitudes. Smaller but significant chlorine activation also is predicted for background aerosol loadings at extreme high latitudes, suggesting chlorine activation can occur on background sulfuric acid aerosol in these regions. The coupling between homogeneous and heterogeneous chemistry is shown to lead to important changes in the concentrations of various reactive species. The basic physical and chemical quantities needed to better constrain the model input parameters are identified." @default.
• W2029884802 created "2016-06-24" @default.
• W2029884802 creator A5013011968 @default.
• W2029884802 creator A5019124017 @default.
• W2029884802 creator A5049434478 @default.
• W2029884802 date "1994-02-20" @default.
• W2029884802 modified "2023-10-17" @default.
• W2029884802 title "Heterogeneous reactions in sulfuric acid aerosols: A framework for model calculations" @default.
• W2029884802 cites W1623924183 @default.
• W2029884802 cites W1815383783 @default.
• W2029884802 cites W1926950498 @default.
• W2029884802 cites W1936252359 @default.
• W2029884802 cites W1977321796 @default.
• W2029884802 cites W1987036651 @default.
• W2029884802 cites W1996306476 @default.
• W2029884802 cites W1996323107 @default.
• W2029884802 cites W2003266253 @default.
• W2029884802 cites W2007423854 @default.
• W2029884802 cites W2018201460 @default.
• W2029884802 cites W2019847833 @default.
• W2029884802 cites W2024976312 @default.
• W2029884802 cites W2035337681 @default.
• W2029884802 cites W2036922617 @default.
• W2029884802 cites W2038114037 @default.
• W2029884802 cites W2040521802 @default.
• W2029884802 cites W2047681527 @default.
• W2029884802 cites W2051877487 @default.
• W2029884802 cites W2053250079 @default.
• W2029884802 cites W2061621310 @default.
• W2029884802 cites W210583670 @default.
• W2029884802 cites W2112012827 @default.
• W2029884802 cites W2133765028 @default.
• W2029884802 cites W2149232040 @default.
• W2029884802 cites W2166668914 @default.
• W2029884802 cites W256108447 @default.
• W2029884802 cites W3157959223 @default.
• W2029884802 cites W62687064 @default.
• W2029884802 doi "https://doi.org/10.1029/93jd02932" @default.
• W2029884802 hasPublicationYear "1994" @default.
• W2029884802 type Work @default.
• W2029884802 sameAs 2029884802 @default.
• W2029884802 citedByCount "406" @default.
• W2029884802 countsByYear W20298848022012 @default.
• W2029884802 countsByYear W20298848022013 @default.
• W2029884802 countsByYear W20298848022014 @default.
• W2029884802 countsByYear W20298848022015 @default.
• W2029884802 countsByYear W20298848022016 @default.
• W2029884802 countsByYear W20298848022017 @default.
• W2029884802 countsByYear W20298848022018 @default.
• W2029884802 countsByYear W20298848022019 @default.
• W2029884802 countsByYear W20298848022020 @default.
• W2029884802 countsByYear W20298848022021 @default.
• W2029884802 countsByYear W20298848022022 @default.
• W2029884802 countsByYear W20298848022023 @default.
• W2029884802 crossrefType "journal-article" @default.
• W2029884802 hasAuthorship W2029884802A5013011968 @default.
• W2029884802 hasAuthorship W2029884802A5019124017 @default.
• W2029884802 hasAuthorship W2029884802A5049434478 @default.
• W2029884802 hasConcept C121332964 @default.
• W2029884802 hasConcept C127313418 @default.
• W2029884802 hasConcept C151730666 @default.
• W2029884802 hasConcept C163861444 @default.
• W2029884802 hasConcept C177801218 @default.
• W2029884802 hasConcept C178790620 @default.
• W2029884802 hasConcept C179104552 @default.
• W2029884802 hasConcept C185592680 @default.
• W2029884802 hasConcept C2778199549 @default.
• W2029884802 hasConcept C2779343474 @default.
• W2029884802 hasConcept C2779345167 @default.
• W2029884802 hasConcept C49999975 @default.
• W2029884802 hasConcept C505241676 @default.
• W2029884802 hasConcept C508106653 @default.
• W2029884802 hasConcept C66882249 @default.
• W2029884802 hasConcept C91586092 @default.
• W2029884802 hasConcept C97355855 @default.
• W2029884802 hasConceptScore W2029884802C121332964 @default.
• W2029884802 hasConceptScore W2029884802C127313418 @default.
• W2029884802 hasConceptScore W2029884802C151730666 @default.
• W2029884802 hasConceptScore W2029884802C163861444 @default.
• W2029884802 hasConceptScore W2029884802C177801218 @default.
• W2029884802 hasConceptScore W2029884802C178790620 @default.
• W2029884802 hasConceptScore W2029884802C179104552 @default.
• W2029884802 hasConceptScore W2029884802C185592680 @default.
• W2029884802 hasConceptScore W2029884802C2778199549 @default.
• W2029884802 hasConceptScore W2029884802C2779343474 @default.
• W2029884802 hasConceptScore W2029884802C2779345167 @default.
• W2029884802 hasConceptScore W2029884802C49999975 @default.
• W2029884802 hasConceptScore W2029884802C505241676 @default.
• W2029884802 hasConceptScore W2029884802C508106653 @default.
• W2029884802 hasConceptScore W2029884802C66882249 @default.
• W2029884802 hasConceptScore W2029884802C91586092 @default.
• W2029884802 hasConceptScore W2029884802C97355855 @default.
• W2029884802 hasIssue "D2" @default.
• W2029884802 hasLocation W20298848021 @default.
• W2029884802 hasOpenAccess W2029884802 @default.
• W2029884802 hasPrimaryLocation W20298848021 @default.
• W2029884802 hasRelatedWork W1531601525 @default.
• W2029884802 hasRelatedWork W2131148861 @default.

• next