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- W2029894804 abstract "Nanocrystalline Ce1-xZrxO2 hollow nanospheres were successfully synthesized via supercritical anti-solvent precipitation using supercritical CO2 as the anti-solvent. It was found that the as-produced samples exhibited hollow spherical structures with uniform diameters ranging from 30 to 50 nm and the sphere walls were composed of various oriented nanocrystallites, with sizes of 3-7 nm. The results of high-resolution transmission electron microscopy showed that the formation of the hollow structures could be controlled by adjusting the solution concentration. The results of temperature-programmed reduction and oxygen storage capacity measurements showed that the hollow nanospheres had enhanced redox properties. A possible mechanism for the formation of Ce1-xZrxO2 hollow nanospheres has also been proposed and experimental investigated." @default.
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- W2029894804 date "2012-01-01" @default.
- W2029894804 modified "2023-10-18" @default.
- W2029894804 title "Controllable synthesis of Ce1−xZrxO2 hollow nanospheres via supercritical anti-solvent precipitation" @default.
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- W2029894804 doi "https://doi.org/10.1016/j.matchar.2011.11.012" @default.
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