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- W2029895544 abstract "Inclusion complex formation between the explosive molecules of the nitramine type, RDX, HMX and TNAZ, and cyclodextrins (α, β and γ) was studied in aqueous solution by means of 1H spin–lattice relaxation time (T1) measurements. The results show that nitramines bind to cyclodextrins in solution; RDX and HMX bind most strongly to γ-cyclodextrin whereas TNAZ binds most strongly to β-cyclodextrin. The dynamic coupling coefficient and dissociation constant were determined for the complex of TNAZ with β-cyclodextrin. The values obtained suggest that TNAZ forms a relatively weak complex with β-cyclodextrin (Kd = 1.8 × 10−2 M) that displays considerable motion in the complex with respect to cyclodextrin (coupling coefficient = 0.23). This method of using 1H T1 measurements for characterizing complex formation in solution, while limited to guest molecules containing a pair of protons having a fixed internuclear distance, is shown to be useful when complexation-induced chemical shifts are too small to be significant." @default.
- W2029895544 created "2016-06-24" @default.
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- W2029895544 date "1993-08-01" @default.
- W2029895544 modified "2023-10-01" @default.
- W2029895544 title "Molecular complexes of explosives with cyclodextrins I. Characterization of complexes with the nitramines RDX, HMX and TNAZ in solution by1H NMR spin-lattice relaxation time measurements" @default.
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- W2029895544 doi "https://doi.org/10.1002/mrc.1260310808" @default.
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