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- W2029916062 endingPage "5691" @default.
- W2029916062 startingPage "5681" @default.
- W2029916062 abstract "Photoinduced reactions of bidentate metal complexes Mg+(2-methoxyethanol), Mg+(1,2-dimethoxyethane), and Mg+(1,2-diaminoethane) have been studied combining mass-selective photodissociation spectroscopy and quantum mechanical calculations. Besides the evaporative fragment cation Mg+, copious reactive channel photoproduct cations have been identified, which are propagated from the well-defined bidentate chelation structures upon photoexcitation of Mg+. For Mg+(2-methoxyethanol) and Mg+(1,2-dimethoxyethane), most reactive channel photoproducts are actually Mg+−molecule complexes, such as Mg+(H2O), Mg+(HCHO), Mg+(CH3OH), Mg+(C2H6O), etc. with an exception of Mg+OH. The reactive channel photoproducts of Mg+(1,2-diaminoethane) consist of a cationic complex Mg+(H2NCH3) and two other cations CH2NH2+ and Mg+NH2, which are formed from the cleavage of the C−C and C−N bonds, respectively. Action spectra and branching fractions of all of the observed photofragments have been measured in a broad spectral range of 230−440 nm and analyzed against ab initio calculations. A hydrogen shift mechanism is proposed, whereby a critical hydrogen-shift step opens doors to the subsequent reactions. This mechanism appears to run through most photoreactions of the three complexes." @default.
- W2029916062 created "2016-06-24" @default.
- W2029916062 creator A5041851178 @default.
- W2029916062 creator A5053717788 @default.
- W2029916062 creator A5087718636 @default.
- W2029916062 date "2003-07-01" @default.
- W2029916062 modified "2023-10-12" @default.
- W2029916062 title "Photodissociation of Bidentate Metal Complex Cations−Hydrogen Shift Reactions" @default.
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