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• W2029932274 abstract "Abstract Phase transformations have been studied in glasses related in composition to Li2O-MgO-SiO2 (930° C) eutectic glass modified by Al 2 O 3 Li 2 O replacement on a cation per cation basis. Crystallization processes and changes in the solid solutions of the mineral phases developed during the controlled heating of the glasses have been followed using X-ray and microscopic techniques. Solid solutions of lithia aluminosilicate phases (B-eucryptite and/or B-spodumene s.s.) are the essential minerals that crystallize in glasses through most of the heat treatment applied. Lithium metasilicate, disilicate, clinoenstatite and cordierite are also encountered. B-eucryptite s.s. is formed in early stage of crystallization of the glass which transforms into B-spodumene s.s. at higher temperature (800° C). However, in some cases, it persists at temperatures as high as 1000° C. Metastable B-eucryptite-B-quartz s.s. can accomodate considerable amounts of Mg2+ and Al3+ ions in its lattice especially at lower temperature. At higher temperature for long duration, a redistribution of the elements takes place, and the cordierite phase then developed." @default.
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• W2029932274 date "1984-08-01" @default.
• W2029932274 modified "2023-09-27" @default.
• W2029932274 title "Solid solution phases from thermally crystallized Li2O-MgO-Al2O3-SiO2 glasses" @default.
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• W2029932274 doi "https://doi.org/10.1016/0254-0584(84)90022-1" @default.
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