Matches in SemOpenAlex for { <https://semopenalex.org/work/W2029941966> ?p ?o ?g. }
- W2029941966 endingPage "281" @default.
- W2029941966 startingPage "276" @default.
- W2029941966 abstract "Abstract Biocatalytic deracemisation via inversion of rac-2-decanol was accomplished by a combined oxidation/reduction sequence using the same ‘single’ catalyst for both steps. Overall, the (R)-alcohol was inverted to the corresponding (S)-alcohol. Lyophilised cells of various Rhodococci spp. were tested for the unselective oxidation of the racemic sec-alcohol using acetone as the hydrogen acceptor in the first step. For the second step, the stereoselective asymmetric reduction of the corresponding ketone, 2-propanol was employed as the hydrogen donor. Employing lyophilised cells of Rhodococcus sp. CBS 717.73 racemic 2-decanol was transformed to (S)-2-decanol with excellent enantiomeric excess (92% ee) and yield (82% isolated yield) in the combined one-pot oxidation/reduction sequence." @default.
- W2029941966 created "2016-06-24" @default.
- W2029941966 creator A5002106013 @default.
- W2029941966 creator A5009412615 @default.
- W2029941966 creator A5052309255 @default.
- W2029941966 date "2007-02-01" @default.
- W2029941966 modified "2023-10-18" @default.
- W2029941966 title "A biocatalytic one-pot oxidation/reduction sequence for the deracemisation of a sec-alcohol" @default.
- W2029941966 cites W1980410358 @default.
- W2029941966 cites W1982567828 @default.
- W2029941966 cites W2009370325 @default.
- W2029941966 cites W2013160605 @default.
- W2029941966 cites W2015561777 @default.
- W2029941966 cites W2016741858 @default.
- W2029941966 cites W2018699888 @default.
- W2029941966 cites W2021407562 @default.
- W2029941966 cites W2026117532 @default.
- W2029941966 cites W2035122819 @default.
- W2029941966 cites W2053366912 @default.
- W2029941966 cites W2058371435 @default.
- W2029941966 cites W2059693901 @default.
- W2029941966 cites W2071893681 @default.
- W2029941966 cites W2077495295 @default.
- W2029941966 cites W2078913579 @default.
- W2029941966 cites W2080522387 @default.
- W2029941966 cites W2084034897 @default.
- W2029941966 cites W2085441520 @default.
- W2029941966 cites W2108531350 @default.
- W2029941966 cites W2116180834 @default.
- W2029941966 cites W2118167116 @default.
- W2029941966 cites W2137260662 @default.
- W2029941966 cites W2154881052 @default.
- W2029941966 cites W2950895427 @default.
- W2029941966 cites W2952706713 @default.
- W2029941966 cites W2953208322 @default.
- W2029941966 cites W4251996822 @default.
- W2029941966 doi "https://doi.org/10.1016/j.tetasy.2007.01.013" @default.
- W2029941966 hasPublicationYear "2007" @default.
- W2029941966 type Work @default.
- W2029941966 sameAs 2029941966 @default.
- W2029941966 citedByCount "19" @default.
- W2029941966 countsByYear W20299419662012 @default.
- W2029941966 countsByYear W20299419662013 @default.
- W2029941966 countsByYear W20299419662014 @default.
- W2029941966 countsByYear W20299419662015 @default.
- W2029941966 countsByYear W20299419662016 @default.
- W2029941966 countsByYear W20299419662019 @default.
- W2029941966 countsByYear W20299419662022 @default.
- W2029941966 crossrefType "journal-article" @default.
- W2029941966 hasAuthorship W2029941966A5002106013 @default.
- W2029941966 hasAuthorship W2029941966A5009412615 @default.
- W2029941966 hasAuthorship W2029941966A5052309255 @default.
- W2029941966 hasConcept C111335779 @default.
- W2029941966 hasConcept C114157696 @default.
- W2029941966 hasConcept C161790260 @default.
- W2029941966 hasConcept C178790620 @default.
- W2029941966 hasConcept C185592680 @default.
- W2029941966 hasConcept C191503008 @default.
- W2029941966 hasConcept C21951064 @default.
- W2029941966 hasConcept C2524010 @default.
- W2029941966 hasConcept C2778112365 @default.
- W2029941966 hasConcept C2781066024 @default.
- W2029941966 hasConcept C2991733762 @default.
- W2029941966 hasConcept C33923547 @default.
- W2029941966 hasConcept C55493867 @default.
- W2029941966 hasConcept C65024703 @default.
- W2029941966 hasConceptScore W2029941966C111335779 @default.
- W2029941966 hasConceptScore W2029941966C114157696 @default.
- W2029941966 hasConceptScore W2029941966C161790260 @default.
- W2029941966 hasConceptScore W2029941966C178790620 @default.
- W2029941966 hasConceptScore W2029941966C185592680 @default.
- W2029941966 hasConceptScore W2029941966C191503008 @default.
- W2029941966 hasConceptScore W2029941966C21951064 @default.
- W2029941966 hasConceptScore W2029941966C2524010 @default.
- W2029941966 hasConceptScore W2029941966C2778112365 @default.
- W2029941966 hasConceptScore W2029941966C2781066024 @default.
- W2029941966 hasConceptScore W2029941966C2991733762 @default.
- W2029941966 hasConceptScore W2029941966C33923547 @default.
- W2029941966 hasConceptScore W2029941966C55493867 @default.
- W2029941966 hasConceptScore W2029941966C65024703 @default.
- W2029941966 hasIssue "2" @default.
- W2029941966 hasLocation W20299419661 @default.
- W2029941966 hasOpenAccess W2029941966 @default.
- W2029941966 hasPrimaryLocation W20299419661 @default.
- W2029941966 hasRelatedWork W2016058310 @default.
- W2029941966 hasRelatedWork W2084339985 @default.
- W2029941966 hasRelatedWork W2147427301 @default.
- W2029941966 hasRelatedWork W2162235249 @default.
- W2029941966 hasRelatedWork W2339877473 @default.
- W2029941966 hasRelatedWork W2513031782 @default.
- W2029941966 hasRelatedWork W2950538893 @default.
- W2029941966 hasRelatedWork W4213279085 @default.
- W2029941966 hasRelatedWork W4251462019 @default.
- W2029941966 hasRelatedWork W9615 @default.
- W2029941966 hasVolume "18" @default.
- W2029941966 isParatext "false" @default.
- W2029941966 isRetracted "false" @default.
- W2029941966 magId "2029941966" @default.