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- W2029965093 abstract "Alkaline hydrolysis rate constants were measured for dimethyl, diethyl, di-n-butyl, di-iso-butyl, and di-(2-ethylhexyl) phthalate esters in water. A linear free energy relationship (LFER) was established for estimating alkaline hydrolysis rate constants for other phthalate esters. Dimethyl phthalate hydrolyzes to phthalic acid with the mono ester as an intermediate. The rate ratio for the second-order-alkaline hydrolysis rate constants of the diester to the monoester is 12. Water solubilities for dimethyl, diethyl, di-n-butyl, di-n-octyl and di-(2-ethylhexyl) phthalate esters were measured and compared with literature values." @default.
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- W2029965093 date "1980-01-01" @default.
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- W2029965093 title "Phthalate ester hydrolysis: Linear free energy relationships" @default.
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- W2029965093 doi "https://doi.org/10.1016/0045-6535(80)90023-5" @default.
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