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- W2029970070 abstract "The coordination of azaferrocene to cobalt(II) porphyrins (CoP) and the photochemistry of the resulting five- and six-coordinated complexes were studied by electron spin resonance spectroscopy. The five-coordinated complexes CoP(B) (B = azaferrocene) are photostable, whereas the six-coordinated complexes CoP(B)(L) (L O2 or B) eject L on irradation with visible light. Two alternative mechanisms for the photoejection of O2 are proposed. The first involves a photoinduced electron transfer between the cobalt(III) and iron(II) centres in the six-coordinated dioxygen complex and the second is based on the photoejection of azaferrocene (4) from this complex." @default.
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- W2029970070 date "1991-04-01" @default.
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- W2029970070 title "Axial coordination of azaferrocene and dioxygen to cobalt(II) porphyrins. Photochemistry of six-coordinated adducts" @default.
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- W2029970070 doi "https://doi.org/10.1016/1010-6030(91)85040-n" @default.
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