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- W2029989063 abstract "Abstract In a model study, 3‐fluorophenol and 3‐fluoropyridine were converted into the each time four possible carboxylic acids by passing through the corresponding organometallic intermediates. As an attempt to generalize the findings reveals, a restricted set of principles and methods suffices to cope with all standard scenarios. The most valuable and versatile tools for the regiochemically exhaustive functionalization of a great variety of substrate patterns are the optionally site‐selective metalation (either by reagent/substrate matching or by peripheral coordination control), the use of activating or congesting protective groups and the basicity gradient‐driven heavy halogen migration (followed by halogen/metal permutation). (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2005)" @default.
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- W2029989063 date "2005-05-01" @default.
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- W2029989063 title "Converting Core Compounds into Building Blocks: The Concept of Regiochemically Exhaustive Functionalization" @default.
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- W2029989063 doi "https://doi.org/10.1002/ejoc.200400895" @default.
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