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- W2030007029 abstract "Abstract Measurements of 1 H and 35 Cl relaxation times in [Ca·6H 2 O][SnCl 6 ] are reported. The 35 Cl quadrupolar T 1 indicates anion reorientation at temperatures above 250 K, with an activation energy of 29.5 ± 1.0 kJ mol −1 . Measurements at high pressure were also carried out, and the volume of activation for anion reorientation was found to be 8.5 ± 0.2 cm 3 mol −1 . Proton T 1 and T 1 ϱ measurements show the presence of three motions associated with the cation. The first is a 180° flipping motion of the water molecules with an activation energy of 13.7 ± 0.4 kJ mol −1 . The other two motions are derived from an asymmetrical double minimum in T 1 ϱ , and reflect uniaxial ( C 3 or C 4 ) reorientation and isotropic tumbling of the entire cation. The activation energies are 38.1 ± 0.4 and 48 ± 2 kJ mol −1 , respectively." @default.
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- W2030007029 date "1982-11-01" @default.
- W2030007029 modified "2023-09-27" @default.
- W2030007029 title "Relaxation in calcium hexachlorostannate hexahydrate" @default.
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- W2030007029 doi "https://doi.org/10.1016/0022-2364(82)90051-8" @default.
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