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- W2030011704 abstract "Wagner’s 1959 diffusion model of the internal oxidation process provided a method of predicting the rate at which a binary alloy was penetrated by dissolved oxygen as it precipitated the more reactive (but dilute) alloy component. Parabolic kinetics were predicted to depend on oxygen permeability in the unreacted alloy solvent and also, in cases where the reactive component was sufficiently mobile, the diffusion coefficient of the latter. The model has proven very successful, but is restricted to single oxidant-binary alloy systems, in which the precipitated oxide has extremely low solubility. This paper reviews recent results on a number of internal precipitation processes which cannot be described with the Wagner theory. These include formation of low stability carbides and nitrades; internal precipitation driven by multiple oxidants; the templating effects of prior precipitates on subsequently formed corrosion products; cellular precipitation morphologies; internal interface diffusion effects; volume changes in the reaction zone and the effects upon them of simultaneous external scaling." @default.
- W2030011704 created "2016-06-24" @default.
- W2030011704 creator A5049967643 @default.
- W2030011704 date "2011-09-01" @default.
- W2030011704 modified "2023-09-30" @default.
- W2030011704 title "Predicting Internal Oxidation: Building on the Wagner Model" @default.
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- W2030011704 doi "https://doi.org/10.4028/www.scientific.net/msf.696.1" @default.
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