FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2030122692> ?p ?o ?g. }

• W2030122692 endingPage "11769" @default.
• W2030122692 startingPage "11762" @default.
• W2030122692 abstract "UV resonance Raman (UVRR) excitation profiles and Raman depolarization ratios were measured for a 21-residue predominantly alanine peptide, AAAAA(AAARA) 3A (AP), excited between 194 and 218 nm. Excitation within the pi-->pi* electronic transitions of the amide group results in UVRR spectra dominated by amide vibrations. The Raman cross sections and excitation profiles provide information about the nature of the electronic transitions of the alpha-helix and polyproline II (PPII)-like peptide conformations. AP is known to be predominantly alpha-helical at low temperatures and to take on a PPII helix-like conformation at high temperatures. The PPII-like and alpha-helix conformations show distinctly different Raman excitation profiles. The PPII-like conformation cross sections are approximately twice those of the alpha-helix. This is due to hypochromism that results from excitonic interactions between the NV 1 transition of one amide group with higher energy electronic transitions of other amide groups, which decreases the alpha-helical NV 1 (pi-->pi*) oscillator strengths. Excitation profiles of the alpha-helix and PPII-like conformations indicate that the highest signal-to-noise Raman spectra of alpha-helix and PPII-like conformations are obtained at excitation wavelengths of 194 and 198 nm, respectively. We also see evidence of at least two electronic transitions underlying the Raman excitation profiles of both the alpha-helical and the PPII-like conformations. In addition to the well-known approximately 190 nm pi-->pi* transitions, the Raman excitation profiles and Raman depolarization ratio measurements show features between 205-207 nm, which in the alpha-helix likely results from the parallel excitonic component. The PPII-like helix appears to also undergo excitonic splitting of its pi-->pi* transition which leads to a 207 nm feature." @default.
• W2030122692 created "2016-06-24" @default.
• W2030122692 creator A5001158948 @default.
• W2030122692 creator A5033842447 @default.
• W2030122692 creator A5062058617 @default.
• W2030122692 date "2008-08-20" @default.
• W2030122692 modified "2023-10-13" @default.
• W2030122692 title "UV Resonance Raman Investigation of Electronic Transitions in α-Helical and Polyproline II-Like Conformations" @default.
• W2030122692 cites W1536836616 @default.
• W2030122692 cites W181814679 @default.
• W2030122692 cites W1964772263 @default.
• W2030122692 cites W1965306829 @default.
• W2030122692 cites W1967682655 @default.
• W2030122692 cites W1974253064 @default.
• W2030122692 cites W1975456002 @default.
• W2030122692 cites W1978732133 @default.
• W2030122692 cites W1990127115 @default.
• W2030122692 cites W1991326083 @default.
• W2030122692 cites W1994301377 @default.
• W2030122692 cites W1996343478 @default.
• W2030122692 cites W1996767323 @default.
• W2030122692 cites W1997875278 @default.
• W2030122692 cites W1999613272 @default.
• W2030122692 cites W2000554658 @default.
• W2030122692 cites W2000636326 @default.
• W2030122692 cites W2000945269 @default.
• W2030122692 cites W2006133412 @default.
• W2030122692 cites W2007116809 @default.
• W2030122692 cites W2007417381 @default.
• W2030122692 cites W2014086437 @default.
• W2030122692 cites W2014126305 @default.
• W2030122692 cites W2019090846 @default.
• W2030122692 cites W2021854187 @default.
• W2030122692 cites W2022165499 @default.
• W2030122692 cites W2025733619 @default.
• W2030122692 cites W2028010350 @default.
• W2030122692 cites W2028339973 @default.
• W2030122692 cites W2029876389 @default.
• W2030122692 cites W2031538415 @default.
• W2030122692 cites W2035652791 @default.
• W2030122692 cites W2037493984 @default.
• W2030122692 cites W2042569387 @default.
• W2030122692 cites W2043338841 @default.
• W2030122692 cites W2048687118 @default.
• W2030122692 cites W2055307767 @default.
• W2030122692 cites W2076969786 @default.
• W2030122692 cites W2079471203 @default.
• W2030122692 cites W2081254445 @default.
• W2030122692 cites W2082996713 @default.
• W2030122692 cites W2083219962 @default.
• W2030122692 cites W2083474842 @default.
• W2030122692 cites W2083978377 @default.
• W2030122692 cites W2085069429 @default.
• W2030122692 cites W2088569178 @default.
• W2030122692 cites W2089055781 @default.
• W2030122692 cites W2090240728 @default.
• W2030122692 cites W2090999957 @default.
• W2030122692 cites W2098745586 @default.
• W2030122692 cites W2104291541 @default.
• W2030122692 cites W2111568960 @default.
• W2030122692 cites W2121285199 @default.
• W2030122692 cites W2130940058 @default.
• W2030122692 cites W2134557860 @default.
• W2030122692 cites W2134666319 @default.
• W2030122692 cites W2150598266 @default.
• W2030122692 cites W2154885222 @default.
• W2030122692 cites W2171570922 @default.
• W2030122692 cites W2315364905 @default.
• W2030122692 cites W2322606775 @default.
• W2030122692 cites W2494690972 @default.
• W2030122692 cites W4233333869 @default.
• W2030122692 doi "https://doi.org/10.1021/jp801110q" @default.
• W2030122692 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/2958432" @default.
• W2030122692 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/18712913" @default.
• W2030122692 hasPublicationYear "2008" @default.
• W2030122692 type Work @default.
• W2030122692 sameAs 2030122692 @default.
• W2030122692 citedByCount "25" @default.
• W2030122692 countsByYear W20301226922012 @default.
• W2030122692 countsByYear W20301226922013 @default.
• W2030122692 countsByYear W20301226922015 @default.
• W2030122692 countsByYear W20301226922016 @default.
• W2030122692 countsByYear W20301226922017 @default.
• W2030122692 countsByYear W20301226922019 @default.
• W2030122692 countsByYear W20301226922020 @default.
• W2030122692 countsByYear W20301226922023 @default.
• W2030122692 crossrefType "journal-article" @default.
• W2030122692 hasAuthorship W2030122692A5001158948 @default.
• W2030122692 hasAuthorship W2030122692A5033842447 @default.
• W2030122692 hasAuthorship W2030122692A5062058617 @default.
• W2030122692 hasBestOaLocation W20301226922 @default.
• W2030122692 hasConcept C109300003 @default.
• W2030122692 hasConcept C120665830 @default.
• W2030122692 hasConcept C121332964 @default.
• W2030122692 hasConcept C139210041 @default.
• W2030122692 hasConcept C184779094 @default.
• W2030122692 hasConcept C185592680 @default.
• W2030122692 hasConcept C18903297 @default.

• next