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- W2030143563 abstract "The liquid-structure factors of fluid rubidium are calculated for a series of states along the saturated-vapor-pressure curve, ranging from temperatures close to the melting point up to the critical point. The calculation is based on the optimized random-phase approximation and on effective interatomic pair potentials derived from pseudopotential perturbation theory. The results are compared with the static-structure factors measured using elastic neutron scattering. Good agreement is found for temperatures up to $T=1400$ K. From the divergence of $S(0)$ the critical temperature is calculated to be ${T}_{c}=2120ifmmodepmelsetextpmfi{}5$ K, compared with an experimental value of ${T}_{c}=2090ifmmodepmelsetextpmfi{}20$ K. The calculation reproduces the strong increase of the long-wavelength scattering, but we find it to be confined to a narrower temperature interval below ${T}_{c}$. We bring evidence that this is due to the breakdown of the nearly-free-electron approximation in a regime where the mean free path of the electrons becomes smaller than the average interatomic distance." @default.
- W2030143563 created "2016-06-24" @default.
- W2030143563 creator A5064795091 @default.
- W2030143563 creator A5090003078 @default.
- W2030143563 date "1984-06-01" @default.
- W2030143563 modified "2023-09-26" @default.
- W2030143563 title "Optimized random-phase approximation for the structure of expanded fluid rubidium" @default.
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- W2030143563 doi "https://doi.org/10.1103/physreva.29.3310" @default.
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