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- W2030170728 abstract "The substitution of [4] B for [4] Si in tourmaline has been the source of much discussion. A sample of olenite from Stoffhutte, Koralpe, Styria, Austria has been found to contain more than one [4] B per formula unit of 31 (O,OH,F), demonstrating that significant [4] B = [4] Si substitution does indeed occur in tourmaline. The composition of the structurally characterized crystal was determined using electron microprobe and SIMS data; in combination with refinement of the site scattering, the chemical data yield an optimized formula of Y (Na 0.400 Ca 0.294 □ 0.306 ) Z (Al 2.424 Li 0.357 □ 0.219 ) (Al 5.916 □ 0.084 ) B 3.00 (Si 4.854 B 1.062 Al 0.084 ) ∑ 6.00 O 27 [F 0.06 (OH) 3.31 O 0.63 ]. The Austrian olenite crystallizes in space group R 3 m , a 15.731(3), c 7.0638(9) A. The atomic arrangement was refined to R = 0.014 using X-ray data; O > is equal to 1.609 A, reflecting substitution of the smaller boron atom for Si. Conjecture on the pattern of distribution of [4] B can be made on the basis of X -site occupancy." @default.
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- W2030170728 date "2000-08-01" @default.
- W2030170728 modified "2023-10-13" @default.
- W2030170728 title "TETRAHEDRALLY COORDINATED BORON IN A TOURMALINE: BORON-RICH OLENITE FROM STOFFHUTTE, KORALPE, AUSTRIA" @default.
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- W2030170728 doi "https://doi.org/10.2113/gscanmin.38.4.861" @default.
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